Device and method for fixing a toner image using a directed stream of solvent vapour

ABSTRACT

A device and method for fixing a tone image on a support material ( 22 ) uses solvent vapour. A directed stream ( 34 ) containing solvent vapour is produced, this stream being directed at a section of the support material ( 22 ) using a nozzle device ( 36 ).

[0001] The invention is directed to a device and to a method for fixing a toner image on a carrier material, whereby the toner image is charged with a solvent vapor. The invention is also directed to an apparatus for printing and/or copying wherein such a device is utilized.

[0002] In numerous electrophotographic printing or copying processes, a toner image is transferred onto a carrier material, for example paper, said toner image being initially not joined to the carrier material in smear-proof and abrasion-resistant fashion. That the toner image is firmly joined to the carrier material, i.e. fixed, is only achieved by a fixing process. A fixing process is usually employed wherein the toner is charged with heat and pressure. The toner is thereby melted with the assistance of heating fixing drums and pressed into the carrier material, so that the toner enters into a bonded union with the carrier material. When no specific pre-heating of the paper is undertaken, this heat-pressure fixing is limited to the transport velocity of the carrier material, for example to approximately 0.5 m/s through 0.7 m/s.

[0003] When the carrier material is simultaneously printed on both sides in the operating mode of duplex printing and both sides are to be simultaneously fixed, then fixing drums that are soft and yielding must be employed at both sides. Such fixing drums have only a short service life and, due to the slight economic feasibility, are only utilized in printers or copiers having a low printing volume. Due to the resilience of the fixing drums, further, the guidance of the carrier material is problematical, so that an endless carrier material web can only be conditionally employed given such a fixing method.

[0004] Contactless fixing methods have already been proposed that avoid the problems arising due to the contact between carrier material and parts of the fixing mechanism, for example the fixing drums.

[0005] EP-A-0 629 930 discloses an arrangement wherein toner is melted with infrared radiation and fixed on the paper. Such an arrangement can also be employed in duplex printing, whereby toner images are simultaneously fixed on both sides of the carrier material. When switched on and off, the infrared radiators that are employed have a relatively great time constant, so that a start/stop mode cannot be realized with such an arrangement without spoilage or rejects.

[0006] DE-A-198 27 210 discloses an arrangement wherein infrared radiation is likewise employed for fixing. A start/stop mode without rejects can be realized by means of the designational control of a blind that is inserted into and in turn withdrawn from the beam path of the infrared radiation. However, the general disadvantage of fixing with the assistance of infrared radiation remains, this being comprised therein that the carrier material, generally paper, is relatively intensely dried during the fixing event, this leading to a shrinkage, to ripple and to an electrostatic charging given further-processing and post-processing of the carrier material. Such a modification of the carrier material can lead to considerable problems in the post-processing of the carrier material, for example when cutting, stacking, binding, enveloping, etc.

[0007] Another known contactless fixing method is photoflash fixing wherein the toner is fixed on the carrier material with high-energy light pulses. The wavelength of the radiation generally lies in the visible through ultraviolet range of the radiation spectrum. Photoflash fixing reacts sensitively to the color of the toner, i.e. the toner material absorbs the energy dependent on the existing light spectrum, which can lead to quality losses given employment of toners having different color, for example in multi-color printing.

[0008] Another contactless fixing method is what is referred to as cold fixing. In this cold fixing, the toner material is softened under the influence of a solvent. The softened toner thereby moistens the carrier material. Given employment of fiber material that contains fibers such as, for example, paper or textiles, the softened toner surrounds the fibers and, due to capillary forces, penetrates between the fibers and into them. After the evaporation of the solvent, the toner in turn congeals and solidifies. In this way, the toner is joined to the carrier material smear-proof and abrasion-resistant. The presence of the solvent in vapor form during the fixing process is more advantageous than the presence as aerosol or liquid, since chemical solvent processes sequence on a molecular basis and a molecular distribution of the solvent is thus the most suitable. Given the employment of vapor, moreover, a condensation of the solvent vapor onto the toner particles occurs due to the different temperatures of carrier material and vapor, so that the vapor molecules deposit directly onto these toner particles. Moreover, the output of the evaporation enthalpy in the condensation supports the softening of the toner and increases the speed of the dissolving process.

[0009] A general advantage of fixing with the assistance of a solvent is the slight thermal stressing of the carrier material. Accordingly, carrier materials can be employed that withstand only a slight thermal or mechanical load such as, for example, labels or films. Moreover, the moisture content of the carrier material is not changed, so that a ripple, a bagging or a curling arising due to changes in moisture are avoided. Moreover, cold fixing is largely independent of the thickness of the carrier material, so that, for example, papers having different paper thicknesses can be employed without a great modification of the fixing process. In this way, a change in the type of paper can also ensue with little outlay.

[0010] U.S. Pat. No. 4,311,723 discloses an arrangement wherein a paper web is conducted through a fixing chamber with solvent vapor. The solvent vapor is situated in a container. Due to the force of gravity as well as cooling tubes in the upper region of the container, the concentration of the solvent vapor increases toward the floor of the container, so that a region with a high solvent concentration arises in the proximity of the container floor. The carrier material, which enters in the upper region of the container with the as yet unfixed toner images, is deflected downward at a first deflection device and is conducted in the region of the high solvent concentration in the proximity of the container floor. The carrier material with partially fixed toner images is deflected again thereat at a second deflection device and is ultimately conducted upward out of the container via a third deflection device. Of necessity, a touching of the carrier material occurs at the deflection devices, as a result whereof the toner situated thereon can smear or peel off or print locations are left behind. It is therefore not possible with this arrangement to fix carrier material charged with toner images on both sides. Moreover, the arrangement exhibits a relatively slow start/stop behavior since—for stopping the fixing—the deflection device must be moved out of the region of high solvent concentration upward into a region having a low solvent concentration with which a fixing no longer ensues, a certain time be required for this.

[0011] The employment of solvent can be problematical in view of the creation of ozone. One speaks of the ozone potential of a solvent in this context. In said U.S. Pat. No. 4,311,723, an azeotropic mixture of tri-chlorofluorethane (C₂Cl₂F₃, CFC1130 and acetone (C₆H₆O) is employed. The primary solvent is the acetone, whereas the CFC113 serves as flame retardant. The use of CFC113 was outlawed in the earlier 1990s due to the high ozone potential. Partially halogenated hydrocarbons, what are referred to as HCFC, were then proposed as replacement for the CFC113, for example HCFC123 and HCFC141b, since these have a significantly lower ozone potential.

[0012] These partially halogenated hydrocarbons HCFC henceforth assumed the function of the flame retardant in mixtures of air and combustible solvents such as acetone, propyl alcohols, etc. In particular, the use of pure HCFC141b without addition of a solvent such as, for example, acetone proved advantageous given employment of polystyrol-based toners since HCFC141b has an adequate fixing action for these toners and is simple to recover as a single-phase material since no mixing or, respectively, de-mixing problems occur.

[0013] Due to its ozone potential and the environmental pollution produced as a result thereof, however, HCFC141b will only be available for a limited time. New fixative mixtures on the basis of chlorine-free, fully halogenated hydrocarbons HFC were therefore proposed, for example in EP-A-0 784 238 (Solvay) and EP-A-0 941 503 (Allied Signal). Given the polyester based toners that are usually employed now, however, these mixtures have proven problematical to employ in practice.

[0014] EP-A-0 613 572 discloses a method and a solvent for fixing a toner constructed on the basis of polystyrol. A partially halogenated fluorohydrocarbon having a temperature of ebullition below 35° C. is employed as sole solvent.

[0015] DE-A-2 720 247 discloses a printing process wherein toner is transferred from an intermediate carrier, for example a photoconductor drum onto a recording medium at a transfer printing station. The toner on the photoconductor drum is charged with a solvent vapor such that it becomes sticky. The recording medium, for example the paper, is likewise exposed to the solvent vapor. The sticky toner adheres on the paper, which is likewise provided with solvent, as a result whereof the transfer printing event and the fixing of the toner ensue in s single process.

[0016] DE-A-2 613 066 discloses a fixing process for fixing toner images on paper.

[0017] Hot gas with a predetermined proportion of water steam is employed for the non-contacting fixing.

[0018] DE-A-2 613 066 also discloses a fixing device wherein the toner material of the toner image on the recording medium is charged with a hot gas, particularly air.

[0019] The temperature of this gas is such that the toner melts and penetrates into the recording medium, for example paper.

[0020] The following documents are cited in the International Search Report:

[0021] CH,A,457 144; U.S. Pat. No. 3,680,795; “Cut-Sheet Vapor Fuser”, IBM Technical Disclosure Bulletin, IBM Corp. New York 32 (3A), 1989, 258-259, XP000049471; DE,A,29 27 453; DE,A,36 36 324.

[0022] The independent claims proceed from the Prior Art according to CH,A,457 144.

[0023] An object of the invention is to specify a device and a method that enables a fixing of toner images with high efficiency given low environmental pollution. This object is achieved by the features of claim 1 for a device. According to further aspects of the invention, an apparatus is recited for printing or copying that employs said device. A method for fixing toner images is also recited.

[0024] Exemplary embodiments of the invention are explained below on the basis of the drawing, whereby known fixing mechanisms are also referenced. Shown in the Figures are:

[0025]FIG. 1 a known fixing device with solvent vapor that is largely at rest;

[0026]FIG. 2 the structure of an inert air layer between the paper web and the solvent vapor;

[0027]FIG. 3 the effect of a solvent depletion;

[0028]FIG. 4 the inventive principle of blowing the carrier material with a directed stream;

[0029]FIG. 5 the schematic structure of a fixing device according to the invention;

[0030]FIG. 6 a preferred exemplary embodiment of the invention wherein the carrier material is blown from above and below;

[0031]FIG. 7 an exemplary embodiment wherein the counter-current principle is realized;

[0032]FIG. 8 the generation of the directed stream by expansion of the evaporating solvent;

[0033]FIG. 9 a simplified version according to FIG. 8;

[0034]FIG. 10 an example with evaporator chambers that are arranged outside the fixing chamber;

[0035]FIG. 11 an exemplary embodiment wherein the carrier material is charged with a directed stream from only one side;

[0036]FIG. 12 the example according to FIG. 11 but with counter-current principle realized therein;

[0037]FIG. 13 two series-connected fixing chambers;

[0038]FIG. 14 the example according to FIG. 13, whereby the co-current flow principle is realized in one chamber and the counter-current principle is realized in the other chamber;

[0039]FIG. 15 two series-connected circulations with solvent vapor in a single chamber;

[0040]FIG. 16 an embodiment wherein the carrier material is vertically conducted through the fixing chamber;

[0041]FIG. 17 an exemplary embodiment wherein the carrier material is conducted through the fixing chamber at an angle of 45°;

[0042]FIG. 18 the exemplary embodiment according to FIG. 6, whereby the control flaps are pivoted into the deflection position; and

[0043]FIG. 19 an exemplary embodiment with further control elements.

[0044]FIG. 1 shows the structure of a traditional fixing device similar to that according to the aforementioned U.S. Pat. No. 4,311,723. In order to understand the exemplary embodiments of the invention better, this known fixing device shall be discussed first. A solvent vapor 12 is generated in a container 10. Cooling tubes 16 that cool the solvent vapor are arranged inside the container 10. Accordingly, the solvent concentration in the upper region 18 is lower than in a middle region 20 and is in turn lower in the latter than in the floor region 14. The highest solvent concentration is thus encountered in this floor region 14. The carrier material 22, generally a paper web, with as yet unfixed toner images enters horizontally into the container 10 and is deflected vertically downward at a first deflection device 24 and is guided into the region of high solvent concentration in the floor region 14. The toner images are partially fixed over this path of the paper web 22. The paper web 22 is deflected again at a second deflection device 26 and is ultimately conducted out of the container 10 via a third deflection device 28.

[0045] Of necessity, contact between the paper web 22 and the deflection elements occurs at the deflection devices 24, 26 and 28. Due to this contact, particularly at the elements 24 and 26, the toner can smear or come off and/or print locations can remain behind on the paper web 22. A double-sided, simultaneous fixing of toner images on both sides of the paper web 22, as would be necessary given the operating mode of duplex printing, is not possible since the toner on the back side would already be smeared at the first deflection device 24. Moreover, the still soft toner could in turn be partially stripped off at the third deflection device 28.

[0046] The device shown in FIG. 1 also exhibits a relatively slow start/stop behavior when the paper web 22 is arrested during forward transport or, respectively, resumes its transport velocity. For stopping the fixing process, namely, the deflection device 26 is moved from the region with high solvent concentration, the floor region 14, upward into the upper region 18 with low solvent concentration at which the fixing process is greatly reduced. The travel motion consumes a relatively long time and thus defines the dynamic behavior of the overall fixing device.

[0047]FIG. 2 schematically shows an effect that arises due to the motion of the carrier material 22. It must be generally mentioned that paper is preferably employed as carrier material 22; however, other materials such as, for example, films, labels or plastics can also be employed. Given a movement of the paper web 22 in the direction of the arrow P1, air 30 is entrained from outside the fixing device. This air 30 is located as an inert layer between the paper web 22 and the solvent vapor 12, as a result whereof the fixing process is retarded since the solvent vapor 12 must first penetrate the air layer 30. This effect is dependent on the transport velocity of the paper web 22 and on the spatial geometry of the fixing device. This effect is especially pronounced when the solvent vapor 12 is at rest.

[0048]FIG. 3 shows a further effect that particularly occurs when the solvent vapor 12 is at rest. The temperature of the paper web 22 generally lies below the temperature of ebullition of the solvent, so that the solvent vapor 12 condenses at the surface of the paper web 22. A solvent depletion occurs in a zone 32 close to the surface of the paper web 22, so that the surface of the paper web is separated from the highly concentrated solvent vapor 12 and the toner cannot be dissolved any further.

[0049]FIG. 4 shows the principle employed in the invention. The surface of the carrier material, for example the paper web 22, is blown by a directed stream that contains solvent vapor 12. The stream 34 emerges from a nozzle 36. The stream 34 of solvent vapor 12 penetrates the inert air layer 30 and proceeds into a region 38 of the paper surface in order to dissolve the toner thereat.

[0050] The strong convection produced by the flow increases the probability that solvent molecules encounter toner particles during the transit time of the paper web 22 through the fixing device and dissolve the toner. The stream 34 is composed of a mixture of air and solvent vapor. The zone 32 with solvent depletion shown in FIG. 3 cannot form due to the convection, since new solvent vapor 12 is continuously replenished. A high solvent concentration is thus always maintained at the location that is blown against. The effect of this blowing principle is that an adequate dissolving effect is achieved even given a slight chemical dissolving force and the required influencing time is shortened. By shortening this influencing time, the structural size of the fixing device can be diminished with a given paper velocity or the paper velocity can be increased with a given structural size.

[0051]FIG. 5 schematically shows the structure of a fixing device of the invention for a simultaneous double-sided fixing of toner images on the carrier material 22. The fixing device comprises a fixing chamber 40 that has an essentially closed structure in order to prevent the active solvent vapor from being diluted with ambient air. The carrier material 22, generally a paper web, traverses the fixing chamber 40 straight and horizontally, whereby it passes through a first, narrow admission gap 42 and a narrow discharge gap 44 lying opposite the former. The admission gap 42 is designed such that no contact occurs between it and the carrier material 22 even when the web of material flutters or sags in order to avoid smearing the toner image situated on both sides of the carrier material 22. When the operating mode of “simplex printing” having only single-sided toner images on the carrier material 22 is applied, contact can occur at that side of the carrier material 22 lying opposite the toner images, and corresponding guide elements can be provided.

[0052] Due to the friction between ambient air and carrier material 22, air is entrained in the region of a boundary layer as a consequence of the transport motion of the carrier material 22. Upon entry of the carrier material 22 into the fixing chamber 40, ambient air is therefore also transported into the fixing chamber 40 through the admission gap 42. As a consequence of the movement of the carrier material 22, solvent vapor is entrained from the inside of the fixing chamber 40 at the discharge side toward the outside through the discharge gap 44. As a result of these effects, the solvent concentration in the inside of the fixing chamber is steadily reduced if this effect is not countered. In order to diminish this effect, first, the admission gap 42 and the discharge gap 44 are implemented optimally narrow; second, fresh solvent vapor is continuously resupplied into the fixing chamber 40 from an evaporator during the fixing process.

[0053]FIG. 6 shows a preferred exemplary embodiment of the invention wherein toner images can be fixed on both sides of the carrier material 22 the fixing device is symmetrically constructed relative to the carrier material web 22. Components are explained below that are required for the fixing of the toner images present on the upper side of the carrier material web 22. An evaporator 22 to which liquid solvent is supplied via a delivery tube 48 is arranged inside the fixing chamber 40. The solvent drips onto a heated plate 50 whose temperature lies above the boiling point of the solvent, for example 30° C. above the boiling point. In order to improve the evaporation process, the plate 50 can be chemically or mechanically roughened or can be provided with channels. The generated vapor stream 52 escapes via an opening 54. This opening 54 can be fashioned as a slot or as a nozzle. In a preferred exemplary embodiment, the opening 54 is fashioned as a valve, preferably as a solenoid valve. The escape of the vapor stream 52 can be controlled by designational, clocked opening and closing of the valve.

[0054] Alternatively, the delivery of the solvent can also ensue with a nozzle. This nozzle (not shown) generates a finely atomized jet of solvent that is sprayed onto the heated plate 50.

[0055] The vapor stream 52 escaping from the evaporator 46 is supplied to the suction side of a cross current ventilator 56 that is fashioned as a radial ventilator. The speed of the cross current ventilator 56 can be regulated in order to set the flow velocity of the stream 34 composed of a mixture of air and solvent vapor. With the assistance of the gap nozzle 36, the stream 34 is directed onto the carrier material 22 obliquely in the transport direction P1 of the carrier material 22. The directed stream 34 is then guided along a channel 58 along the carrier material 22 and is extracted by the cross current ventilator 56 at the end of the channel 58 in order to be compressed to form a directed stream 34 mixed anew with the fresh vapor stream 52. The flow velocity of the stream 34 generally amounts to a multiple of the transport velocity of the carrier material 22. In this way, the same part of the stream 34 with the solvent vapor can repeatedly act on the toner images on the carrier material 22 within an influencing time that is defined by the length of the channel 58 and by the transport velocity.

[0056] The solvent vapor responsible for the dissolving of the toner material is supplied to the toner material in the toner images in a circulation upon continuous circulation of the solvent vapor. The continuous circulation of the solvent produces a homogenization of the solvent concentration within this circulation and, thus, a homogenization of the fixing of the toner images on the carrier material 22. Blowing a directed stream 34 against the carrier material 22 accelerates the fixing event, so that a lower solvent concentration suffices for the fixing or solvents having reduced dissolving power can be employed.

[0057] According to the exemplary embodiment according to FIG. 6, the gap nozzle 36 generates a stream 34 that obliquely impinges the carrier material 22. Due to the oblique positioning of the gap nozzle 36, an under-pressure or, respectively, a constant pressure is produced in the region of the admission gap 42. The entry of air due to the transport motion of the carrier material 22 can thus be minimized by means of a skillful selection of the angle of incidence of the-gap nozzle 36.

[0058] In the example of FIG. 6, components of the directed stream 34 and of the transport direction P1 are isodirectional. Such an arrangement is referred to as a co-current flow principle. The arrangement can also be designed such that components of the stream 34 and of the transport direction P1 are opposite one another. This arrangement is referred to as counter-current principle.

[0059] When the carrier material 26 carries toner images on only one side, for example the upper side, then the component parts for fixing toner images of the lower side can be foregone, i.e. the component parts such as the evaporator, the cross current ventilator, etc., that are arranged under the carrier material in FIG. 6.

[0060] The arrangement according to FIG. 6 can be designed such that combustible solvents that require device-oriented safety measures in the framework of explosion protection can be utilized. An explosion flap 60 that opens given increased pressure is thus arranged in the region of the discharge gap 44. The carrier material 22 is electrostatically discharged by means of ionized air with the assistance of a discharge device 62. All ignition sources within the fixing chamber 40 are avoided. All parts of the apparatus are grounded in order to avoid static charging. A respective extraction device 64, 66 that extracts the solvent vapor escaping from the fixing chamber 40 in slight amounts is arranged in the proximity of the admission gap 42 and of the discharge gap 44. Accordingly, no concentrations of solvent vapor that are explosive or harmful to health can occur outside of the fixing chamber, even given longer operation.

[0061] The arrangement according to FIG. 6 is also designed for a fast start/stop behavior. Two control flaps 70, 72 are provided for this purpose, these being shown in the enable position in FIG. 6. In this position, the stream 34 can flow freely. Both control flaps 70, 72 can be swivelled into a deflection position according to the swivelling directions P2, P4, so that the carrier material 22 no longer has solvent vapor blown against it. For immediate interruption of the fixing process, the control flaps 70, 72 are moved into the deflection position. At the same time, the delivery of solvent via the delivery pipe 48 is stopped for the evaporation process, and the extraction device 66 is turned off. The other extraction device 64 then suctions fresh air into the fixing chamber 40, and the channel 58 and, thus, the region around the carrier material 22 are flooded with fresh air. The fixing process is suddenly interrupted by means of these measures.

[0062] Upon resumption of the printing operations and the further transport of the carrier material 22, the fixing process is restarted by swivelling the control flaps 70, 72 opposite the directions P2, P4. At the same time, the extraction device 66 is reactivated and the admission of solvent for the evaporator 46 is started.

[0063] In certain printing processes, the carrier material 22 is retracted in the direction of the printing unit opposite the direction P1 before the resumption of the printing operations. In this case, the control flaps 70, 72 are not returned into the enable position until unfixed toner images are again situated in the blowing location in the channel 58. What is thus achieved is that toner images that have already been fixed need not undergo the fixing process again.

[0064] A sensor that measures the solvent concentration is connected into the circulation with solvent vapor. As shall be explained in greater detail later, the solvent concentration is regulated to a constant value with the assistance of this sensor 74;

[0065] In the delivery of solvent into the circulation for solvent vapor and in the guidance of the solvent vapor in the circulation, care must be exercised to see that no larger drops of solvent that could fall onto the carrier material 22 form anywhere due to condensation. For this reason, all walls in the fixing chamber that come into contact with the solvent vapor are heated. The temperature of these walls is set such that it at least has the temperature of ebullition of the solvent or lies above this.

[0066]FIG. 7 shows an example of a fixing mechanism similar to FIG. 6. However, the counter-current principle is realized here, i.e. the stream 34 with solvent vapor is directed opposite the transport direction P1 of the carrier material 22.

[0067]FIG. 8 shows another version of the invention. In this version, the expansion of the evaporating solvent is utilized in order to generate a directed stream 34 that contains solvent vapor. Liquid solvent is supplied to the evaporator 46 via the delivery pipe 48. The nozzle 36 generates the directed stream 34 that blows against the carrier material 22. The flow velocity and the volume stream are dependent on the quantity of solvent evaporated. A gap nozzle is also preferably employed here as nozzle 36. However, it is also possible—and this is also true of the other example—to have the solvent vapor flow out from a plurality of small round nozzles that are attached over the width of the carrier material 22. In the example of FIG. 8, the carrier material 22 does not have a vapor stream circulation blowing multiply against it.

[0068]FIG. 9 shows a further version of a fixing device of the invention wherein a directed stream 34 is generated on the basis of the expansion during the evaporation of the solvent. This stream 34 is directed onto the carrier material 22 only once. The version according to fi9 is suited for low transport speeds of the carrier material 22.

[0069]FIG. 10 shows a further version wherein the evaporator 46 is arranged outside the fixing chamber 40. The opening 52 is gap-shaped and is located in the proximity of the cross current ventilator 56 at the suction side thereof. The opening 54, however, can also have other embodiments. Expressed in general terms, the introduction point for the fresh vapor into the circulation can be situated at an arbitrary point of the circulation.

[0070]FIG. 11 shows an exemplary embodiment for simplex printing. The fixing process with the directed stream 34 only takes effect on one side of the carrier material 34. The co-current flow principle is applied in the example according to FIG. 11, whereby the stream 34 proceeds in the direction P1 of the transport of the carrier material 22.

[0071]FIG. 12 shows the example of FIG. 11 with counter-current principle, whereby the stream 34 proceeds opposite the transport direction P1.

[0072]FIG. 13 shows an example wherein two circulations with streams 34 a and 34 b are successively generated. Both stream 34 a, 34 b act on the same side of the carrier material 22. The streams 34 a and 34 b are generated in two series-connected fixing chambers 40 a, 40 b. The synchronous [sic] principle is applied in both chambers chamber 40 a, 40 b.

[0073]FIG. 14 shows an example similar to FIG. 13. The co-current flow principle is applied in the chamber 40 a and the counter-current principle is applied in the chamber 40 b.

[0074]FIG. 15 shows another example similar to that of FIG. 14, whereby, however, the streams 34 a and 34 b are generated in a single fixing chamber 40. The combined co-current/counter-current principle according to the example of FIG. 14 is retained.

[0075]FIG. 16 shows an embodiment wherein the carrier material 22 is vertically conducted through the fixing chamber 40. As a consequence of the forced flow, the fixing process—expressed in general terms—is independent of the transport direction of the carrier material. Greater degrees of freedom thus derive in the design and the incorporation of the fixing device in a printer or copier.

[0076]FIG. 17 shows an example wherein the carrier material 22 is conducted through the fixing chamber 40 at an angle of approximately 40°.

[0077]FIG. 18 shows the exemplary embodiment according to FIG. 6, whereby the control flaps 70 and 72 are swivelled into the deflection position. The stream 34 is deflected with the assistance of these control flaps 70, 72 such that it no longer blows against the carrier material 22. At the same time, the delivery of solvent into the evaporator 46 is stopped and the extraction device 66 is turned off the extraction device 64 that continues to operate then suctions fresh air into the fixing chamber 40, as a result whereof the carrier material 22 is flooded with fresh air. The fixing process is instantly interrupted by means of these measures. For resuming the fixing operations, the control flaps 40, 72 are swivelled back into a position as entered in FIG. 6. At the same time, the extraction device 66 is activated and the solvent delivery into the evaporator 46 is started.

[0078]FIG. 19 shows the fixing device according to FIG. 6 with further control elements. As a result of the steady dragging of air into the fixing chamber 40 that cannot be completely prevented due to the movement of the carrier material 22, solvent must be constantly replenished during the fixing operations in order to maintain the solvent concentration. The sensors 74 a and 74 b serve for detecting the solvent concentration, said sensors acquiring the concentration above the carrier material 22 on the one hand and under the carrier material 22 on the other hand. The signals of the sensors 74 a, 74 b proceed to regulators 80 a, 80 b that act on solenoid valves 76 a, 76 b that are connected into the admission lines 82 a, 82 b for the solvent. In the open condition of the solenoid valves 76 a, 76 b, solvent proceeds from a reservoir 78 to the evaporator chamber 46 a, 46 b. The regulators 80 a, 80 b set the opening times of the solenoid valves 76 a, 76 b such that the solvent concentration in the stream 34 a or, respectively, 34 b has a constant value.

[0079] The advantages of the inventive fixing device shall be summarized again on the basis of the described exemplary embodiments. The illustrated fixing devices make it possible to fix toner images on the carrier material contact-free. The toner image as well as the carrier, for example sensitive paper, are not damaged and no pressure points and no stripping or crushing of the toner arise. Further, wear parts as required, for example, in the form of the fixing drums given heat-pressure fixing are eliminated.

[0080] The fixing device enables an intermittent operation since a fast start/stop mode can be realized. The structural size of the fixing device is relatively small compared to traditional fixing devices and comparable transport speeds, for example transport speeds above 1 m/s. Due to the circulation of the solvent vapor and of the directed stream, a very homogeneous fixing image is achieved.

[0081] The fixing process is improved by blowing the carrier material with solvent vapor and, in particular, due to the circulation principle, so that less solvent given reduced consumption is required. An environmentally safe solvent with reduced dissolving power can likewise be employed, whereby the transport speed can be high, i.e. above 1 m/s. The degree of softening of the toner material can be influenced by the solvent concentration in the fixing chamber. The degree of penetration of the toner into the paper can thus be controlled. For specific demands, for instance increased document security, the fixing device of the invention makes it possible to achieve such a great penetration of the toner into the carrier material that this toner can only be removed from the carrier material with great outlay or cannot be removed therefrom at all.

[0082] Given the recited fixing process, the fixing is largely independent of the thickness of the carrier material; for example, thin and thick papers can be processed. Due to the low temperature prevailing in cold fixing, a low thermal stress derives, so that heat-sensitive carrier materials such as, for example, films and labels can be employed.

[0083] During fixing in the fixing chamber, the carrier material is only slightly heated, so that it is not dehumidified or hardly dehumidified. Changes in moisture are thereby avoided and disadvantageous effects such as ripple, bagging or curling of the carrier material do not occur. Toners having different colors can be simultaneously fixed with the assistance of the described fixing devices.

[0084] The fixing device allows halogen-free solvents to be preferably employed such as, for example, ethyl acetate, acetone, isopropanol, n-propanol. The solvent can be single-phase, as a result whereof the condensation and processing of the solvent vapors that emerge from and are extracted from the fixing chamber are very simple in the framework of a recovery. As a result of this recovery and re-employment of the solvent, the overall solvent consumption can be reduced further.

[0085] Toner having a arbitrary polymer basis such as, for example, on the basis of polystyrol, polyester and others can be utilized. There is generally a suitable solvent for each of these polymers.

[0086] List of Reference Characters

[0087]10 container

[0088]12 solvent vapor

[0089]14 floor region

[0090]16 cooling tubes

[0091]18 upper region

[0092]20 middle region

[0093]22 carrier material

[0094]24 deflection device

[0095]26,28 deflection devices

[0096]30 air

[0097] P1 transport direction of the carrier material

[0098]32 zone with solvent depletion

[0099]34 directed stream

[0100]36 nozzle

[0101]38 blowing point

[0102]40 fixing chamber

[0103]40 a,40 b fixing chambers

[0104]42 admission gap

[0105]44 discharge gap

[0106]46 evaporator

[0107]48 delivery pipe

[0108]50 plate

[0109]52 vapor stream

[0110]54 opening

[0111]56 cross current ventilator

[0112]58 channel

[0113]60 explosion flap

[0114]62 discharge device

[0115]64,66 extraction devices

[0116]70,72 control flaps

[0117] P2,P4 swivelling directions

[0118]74,74 a,74 b sensors

[0119]76 a,76 b solenoid valves

[0120]78 reservoir

[0121]80 a,80 b regulators 

1. Apparatus for fixing a toner image on a carrier material (22), whereby the toner image is charged with a solvent vapor, a directed stream (34) containing solvent vapor is generated, and whereby the stream (343) is directed onto a section of the carrier material (22) with the assistance of a nozzle device (36), characterized in that the solvent vapor is generated inside a fixing chamber (40) whose walls that come into contact with the solvent vapor are heated by heating means to a temperature that is at least equal to or higher than the temperature of ebullition of the solvent.
 2. Apparatus according to claim 1, whereby an acceleration device (56) is provided for generating the stream (34) containing solvent vapor.
 3. Apparatus according to claim 2, whereby a cross current ventilator (56) is provided as acceleration device.
 4. Apparatus according to one of the preceding claims, whereby the solvent vapor not absorbed by the carrier material (22) and the toner image is extracted, is enriched with a predetermined quantity of freshly evaporated solvent, and a stream (34) of solvent vapor that is supplied to the nozzle device (36) is generated anew.
 5. Apparatus according to one of the preceding claims, whereby the carrier material (22) is web-shaped and is preferably paper.
 6. Apparatus according to one of the preceding claims, whereby the carrier material (22) is transported in non-contacting fashion in the region in which it is charged with solvent vapor.
 7. Apparatus according to one of the preceding claims, whereby the carrier material (22) is electrostatically discharged with the assistance of a discharge device (62) before the charging with solvent vapor.
 8. Apparatus according to one of the preceding claims, whereby the stream (34) of solvent vapor is directed in moving direction (P1) of the carrier material (22).
 9. Apparatus according to one of the preceding claims 1 through 7, whereby the stream (34) of solvent vapor is directed opposite the moving direction (P1) of the carrier material (22).
 10. Apparatus according to one of the preceding claims, whereby the stream (34) of solvent vapor is guided along a channel section (58) having a defined length and within which the solvent vapor acts on the toner image and on the carrier material (22).
 11. Apparatus according to one of the preceding claims, whereby a gap nozzle (56) is provided as nozzle device.
 12. Apparatus according to one of the preceding claims, whereby a heated plate (50) onto which liquid solvent is dripped is provided for the evaporation of the solvent.
 13. Apparatus according to claim 12, whereby the solvent is supplied by means of a delivery pipe (48); and whereby the heated plate (50) is preferably chemically or mechanically roughened and/or is provided with channels.
 14. Apparatus according to claim 12 or 13, whereby the solvent is supplied to the heated plate (50) with the assistance of a nozzle that sprays the solvent.
 15. Apparatus according to one of the preceding claims, whereby at least one valve (82 a, 82 b), preferably a solenoid valve, that controls the flow of solvent from a reservoir (78) is provided.
 16. Apparatus according to claim 15, whereby the valve is driven such that a predetermined concentration of solvent is maintained in the stream of solvent vapor.
 17. Apparatus according to claim 15 or 16, whereby at least one sensor (74 a, 74 b) is provided that measures the solvent concentration in the stream (34) of solvent vapor; and in that the concentration of the solvent is regulated by control of the solenoid valve (82 a, 82 b).
 18. Apparatus according to one of the preceding claims, whereby a vapor stream valve is provided that enables or stops the delivery of solvent vapor from and evaporator (46).
 19. Apparatus according to one of the preceding claims, whereby the fixing chamber (40) is secured by at least one explosion flap (60).
 20. Apparatus according to one of the preceding claims, whereby the carrier material (22) is guided in the fixing chamber (40) via an admission gap (42) and a discharge gap (44); and in that a respective extraction device (64, 66) at the admission gap (42) and at the discharge gap (44) extracts solvent vapor.
 21. Apparatus according to one of the preceding claims, whereby at least one control flap (70, 72) is provided with which the stream (34) of solvent vapor is deflected such in a deflection position that the carrier material (22) no longer has solvent vapor blown against it.
 22. Apparatus according to claim
 21. whereby, for the immediate interruption of the fixing process, the control flap (70, 72) is driven into the deflection position; in that the flow of solvent for the evaporation process is stopped and/or one of the extraction devices (66) is turned off.
 23. Apparatus according to one of the preceding claims, whereby, given a stop of the forward transport of the carrier material (22), the fixing process is also stopped.
 24. Apparatus according to one of the preceding claims 21 through 23, whereby, given resumption of the transport of the carrier material, the control flap (70, 72) is swivelled from the deflection position into an enable position for the stream (34) of solvent vapor; the solvent flow for the evaporation process is started and/or whereby the extraction device (66) is reactivated.
 25. Apparatus according to one of the preceding claims, whereby the carrier material (22) inside the fixing chamber is simultaneously respectively charged from both sides with a directed stream (34) of solvent vapor.
 26. Apparatus according to one of the preceding claims 4 through 25, whereby the evaporator (46) for generating the solvent vapor is arranged outside the fixing chamber (40).
 27. Apparatus according to one of the preceding claims, whereby the carrier material (22)—as viewed in transport direction (P1)—is successively charged by a first stream (34 a) containing solvent vapor and then by a second stream (34 b) containing solvent vapor.
 28. Apparatus according to claim 27, whereby the first stream (34 a) and the second stream (34 b) are identically directed.
 29. Apparatus according to claim 27, whereby the first stream (34 a) and the second stream (34 b) are directed opposite one another.
 30. Apparatus according to one of the preceding claims 27 through 29, whereby both streams (34 a, 34 b) are generated in a single chamber.
 31. Apparatus according to one of the preceding claims 27 through 29, whereby each stream (34 a, 34 b) is generated in a chamber (40 a, 40 b).
 32. Apparatus according to one of the preceding claims 4 through 31, whereby the solvent has a low ozone potential.
 33. Apparatus according to claim 32, whereby the solvent is single-phase.
 34. Apparatus according to claim 32 or 33, whereby ester, preferably ethyl acetate, ketone, preferably acetone, or alcohol, preferably isopropanol, n-propanol, trans-1,2-dichloroethylene is employed as solvent.
 35. Apparatus according to one of the preceding claims, whereby toner on the basis of polystyrol is employed.
 36. Apparatus for printing and/or copying, whereby a band-shaped carrier material is printed with toner images on at least one side; whereby the apparatus can be coupled to at least one device according to one of the preceding claims.
 37. Method for fixing a toner image on a carrier material (22), whereby the toner image is charged with a solvent vapor, a directed air stream (34) containing solvent vapor is generated, and whereby the stream (34) is directed onto a section of the carrier material (22) with the assistance of a nozzle device (36), characterized in that the solvent vapor is generated inside a fixing chamber (40) whose walls that come into contact with the solvent vapor are heated by heating means to a temperature that is at least equal to or higher than the temperature of ebullition of the solvent.
 38. Method according to claim 37, whereby an acceleration device (56), preferably a cross current ventilator (56), is provided for generating the stream (34) containing solvent vapor.
 39. Method according to one of the preceding claims 37 or 38, whereby the solvent vapor not absorbed by the carrier material (22) and the toner image is extracted, is enriched with a predetermined quantity of freshly evaporated solvent, and a stream (34) of solvent vapor that is supplied to the nozzle device (36) is generated anew.
 40. Method according to one of the preceding claims 37 through 39, whereby the stream (34) of solvent vapor is directed in moving direction (P1) of the carrier material (22).
 41. Method according to one of the preceding claims 37 through 39, whereby the stream (34) of solvent vapor is directed opposite the moving direction (P1) of the carrier material (22).
 42. Method according to one of the preceding claims 37 through 41, whereby the carrier material (22) inside the fixing chamber is simultaneously respectively charged from both sides with a directed stream (34) of solvent vapor.
 43. Method according to one of the preceding claims 37 through 42, whereby the solvent has a low ozone potential.
 44. Method according to claim 43, whereby the solvent is single-phase.
 45. Method according to claim 43 or 44, whereby ester, preferably ethyl acetate, ketone, preferably acetone, or alcohol, preferably isopropanol, n-propanol, trans-1,2-dichloroethylene is employed as solvent.
 46. Method according to one of the preceding claims 37 through 45, whereby toner on the basis of polystyrol is employed. 